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silicone to prevent solar cell oxidation?

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Hi!

In this video

http://www.youtube.com/watch?v=EEOBYulZ_fI&t=3m48s

the guy says Sylgard 184, a brand of silicone, protects the cells from
moisture, the environment and oxygen. "You won't get 30 years out of
these if they're exposed to oxygen."

Now I wonder two things.

Firstly, isn't silicone "highly" permeable to gas? Does it really
protect from oxygen?

Secondly, is oxygen really a problem? I guess the semiconductor is
immune, cause oxygen forms a highly stable and...

silicone to prevent solar cell oxidation?

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